Skylights and open areas like this create very tricky problems, especially during the ceremony when you don't have the ability to use flash.
For this type of photograph you will need to set your camera so that it is giving you a good exposure for the outside. Now if possible, set your flash .5 to 1 stop higher than the ambient light and shoot. This setting will darken the outside slightly and bring attention to your couple.
The truth behind this shot is that the outside light was too bright for me to overcome during the ceremony. The final fix was to shoot one image during the ceremony which was exposed for the outside and then shoot one which captured the couple. The final image was a sandwhich of the two with some editing done to erase one layer down to the other.
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